She played a woman who is cured from glomerulonephritis through a healer, but must suffer a curse.From this film, she received a number of Best Supporting Actress nominations from almost all of the film award-giving bodies, missing only the Gawad Urian and The Young Critics' Circle.
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She and her on-screen partner Gerald Anderson became regulars in ASAP XV and appeared together in several ABS-CBN shows Love Spell, comedy sitcom Aalog-Alog and in the film First Day High.
In 2007, Chiu starred in the primetime TV series entitled Sana Maulit Muli alongside Anderson which was released to significant acclaim.
She joined the PETA campaign Free Mali along with Xian Lim.
Chiu made a video plea for Mali, asking that she be moved to a sanctuary for the sake of her well being.
In the midst of movie promotions, it was reported that the long-time couple (known as Kimerald) had split, yet the reason for the breakup was not discussed.